Phosphate corrosion in high-pressure boilers OSTI GOV

Water Steam Cycle Chemistry And Corrosion - Uniper

Where boiler pressure (and discharges to water) allow, the use of Tri-Sodium Phosphate is preferred instead of Caustic as the corrosion risks are usually lower (e.g. from mechanical drum carryover).

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Boiler Systems for Industrial Steam Power Plants | GE Steam Power

gas fuel oil two-pass. hot water boiler. Power: 160,000 W. Pressure: 200, 300, 500 bar. Description: This is the right choice if the heating capacity of a single boiler is not enough and no paneling is necessary. Construction and content: Two boiler BR 1000 or BR 1000G

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KNOWLEDGE BASED CONTROL FOR HIGH PRESSURE BOILER WATER TREATMENT

2018/8/23 · Case History, Pulp Plant, High Pressure Recovery Boilers This plant is equipped with two high pressure recovery boilers (85 bar). The boiler water treatment has …

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(PDF) Using Of Congruent Phosphate As Equilibrium Phosphate Boilers Water Treatment …

Phosphate treatment systems used in boilers [1] The most popular treatment for low pressure boilers (< 600 psi) is dosing of tri-sodium phosphate (TSP), it reacts with water at high temperature and gives sodium hydroxide to increase boilers water pH as shown

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High-Pressure Steam Cycle and Boiler Water Treatment

HP and LP Differences • High pressure – Makeup water is very pure and corrosive • Low level of dissolved solids – Based on coordination of phosphate and pH so that no free caustic exists – Lower chemical treatment levels – Lower tolerances for variations in chemical levels and TDS

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(PDF) Boilers and Steam Lines Chemical Cleaning

Corrosion of a tube made up of9Cr-lMo, 2-25Cr-lMo, and 2-25Cr-lMo-Nb ferritic steels and containing artificial defects has been investigated under realistic steam generator conditions (355 C, 17-6

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Using of congruent phosphate as equilibrium phosphate boilers water treatment

Equilibrium phosphate control is based on boilers water treatment by tri-sodium phosphate for low pressure boilers and tri-sodium phosphate added low concentration of sodium hydroxide for high pressure boilers as shown in fig. 1. EPT has no specification to

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Water Treatment for High Pressure Boilers in Sugar Plant

Page 3 of 8 Water treatment is very important in high pressure boilers to protect the system from corrosion, scale and deposits. Total solids and silica are required to be maintained at low levels in drum water at high pressures to maintain desired steam quality.

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Phosphate corrosion in high pressure boilers (Conference) | …

1995/12/1 · Phosphate corrosion is the name given to attack involving phosphate compounds having unique wastage morphologies and associated corrosion products and deposits. Phosphate attack as caustic corrosion in high-pressure boiler tubes. Journal Article Romero, M.F. de ; Perez, O ; Navarro, A - Materials Performance.

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Successful Caustic Treatment Of Electric Utility Drum Boilers | NACE CORROSION …

2009/3/22 · The high boiler water pH also protected boiler surfaces from corrosion. Current Phosphate Treatment Concepts Once acid phosphate corrosion was identified, the use of Congruent Phosphate Treatment (CPT) in high pressure boilers was greatly reduced.

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Water Steam Cycle Chemistry And Corrosion - Uniper

Where boiler pressure (and discharges to water) allow, the use of Tri-Sodium Phosphate is preferred instead of Caustic as the corrosion risks are usually lower (e.g. from mechanical drum carryover).

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14th Annual All Users Conference

Phosphate Corrosion Corrosion by phosphates is an on-going problem in phosphate-treated boilers, especially as pressures have increased. Sodium phosphate is used to buffer boiler water pH. "Congruent control' with phosphates was introduced to prevent the

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What is Acid Phosphate Corrosion? - Definition from Corrosionpedia

2016/10/24 · Boilers, which generally use congruent phosphate pH treatment to prevent caustic corrosion, may in turn be subject to acid phosphate corrosion when boiler water is concentrated beneath deposits. This is the result of a localized concentration of phosphate and the high temperature of …

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Phosphate corrosion in high-pressure boilers (Journal Article) | …

1995/12/1 · Phosphate treatments have been used in boilers for more than 70 years. As operating pressures increased, the frequency of corrosion-related failures in phosphate-treated boilers also increased. Many failures were attributed to ``free`` caustic generated by the nonstoichiometric precipitation of various phosphate compounds on boiler surfaces.

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An automated coordinated phosphate/ph controller for industrial …

1995/12/1 · Phosphate treatments have been used in boilers for more than 70 years. As operating pressures increased, the frequency of corrosion-related failures in phosphate-treated boilers also increased. Many failures were attributed to ``free`` caustic generated by the

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Phosphate attack as caustic corrosion in high-pressure boiler …

1999/3/1 · @article{osti_6441086, title = {Phosphate attack as caustic corrosion in high-pressure boiler tubes}, author = {Romero, M.F. de and Perez, O and Navarro, A}, abstractNote = {Some boiler-tube failures attributed to caustic gouging actually have been caused by reaction of sodium phosphate species with boiler tube steel, boiler tube oxides, or both.

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Phosphate attack as caustic corrosion in high-pressure boiler …

1999/3/1 · @article{osti_6441086, title = {Phosphate attack as caustic corrosion in high-pressure boiler tubes}, author = {Romero, M.F. de and Perez, O and Navarro, A}, abstractNote = {Some boiler-tube failures attributed to caustic gouging actually have been caused by reaction of sodium phosphate species with boiler tube steel, boiler tube oxides, or both.

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(PDF) Using Of Congruent Phosphate As Equilibrium Phosphate Boilers Water Treatment …

Phosphate treatment systems used in boilers [1] The most popular treatment for low pressure boilers (< 600 psi) is dosing of tri-sodium phosphate (TSP), it reacts with water at high temperature and gives sodium hydroxide to increase boilers water pH as shown

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Impact of Boiler Water Chemistry on Waterside Tube Failures

Burton [5]. It was reported that main corrosion damage of high pressure boilers tubing occurs as a result of fouled heat transfer surfaces and by an active corrodent in the boiler water. It has been reported that the vulnerability of high pressure boiler to major

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Plant Service Bulletin: Boiler Water Phosphate Chemistry

sodium phosphates in maintaining the boiler water pH. One of the disadvantages of this treatment is that, on high-pressure drum type units, the detectable concentration of phosphate in the bulk boiler water can decrease with increasing load and pressure, and

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